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Report on the Geology & Gold Fields of Otago

Appendix E. — Analyses of Rocks and Minerals. by Professor J. G. Black

page 146

Appendix E.
Analyses of Rocks and Minerals. by Professor J. G. Black.

Extracted from the Votes and Proceedings of the Provincial Council of Otago, 1875.

Coals.

Eight samples of hydrated brown coal were forwarded from the Tokomairiro coalfield, and without undergoing any previous process of drying, were analysed with the following results:—
Coke from 37 to 41 per cent., averaging 39 per cent.
Fixed Carbon from 30 to 35.5 per cent., averaging 33 per cent.
Volatile Hydrocarbons from 31 to 38 0 per cent., averaging 35.4 per cent.
Ash from 2 to 9 per cent., averaging 5 per cent.
Water from 22 to 30 per cent., averaging 27 per cent.
Five samples of Lignite were sent at various times from different parts of the Green Island field, and without previous drying yielded the following results:—
Coke 38 to 41 per cent., averaging 39 per cent.
Fixed Carbon 35 to 37 per cent., averaging 36 per cent.
Volatile Hydrocarbons 30 to 37 per cent., averaging 34 per cent.
Ash 2.4 to 3.3 per cent., averaging 2.8 per cent.
Water 25.7 to 29 per cent., averaging 27 per cent.
A sample of hydrated brown coal from the Kaitangata coalfield, without artificial drying, yielded:—
Coke 42.1 per cent.
Fixed Carbon 38.7 per cent.
Volatile Hydrocarbons 38.9 per cent.
Ash 3.4 per cent.
Water 18.0 per cent.
A specimen was sent by Mr. McArthur from Nightcaps in Southland. On analysis it showed:—
Coke 45.3 per cent.
Fixed Carbon 41.8 per cent.
Volatile Hydrocarbons 317 per cent.
Ash 3.5 per cent.
Water 23.0 per cent.
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Iron Ores.

Iron Sand.

Three samples of black iron sand from Stewart Island, Taranaki, and Tokomairiro. The iron ranges from 49 to 54 per cent.

Port Molyneux.

This specimen is hydrated sesquoxide of iron from Port Moly neux. It yielded:—
Water 14 per cent.
Oxide of Iron 65.5 per cent.
Earthy matter (clay silica) 20.5 per cent.
This is equal to 46 per cent. of metallic iron. If there is a large quantity of this ore near a good coal field, it should take a good place among the industries of the future. The small quantity of silica present (about 10 per cent.) will not require much lime for its removal.

Maeruwhenua.

This sample was forwarded by Capt. Hutton. It is hydrated sesquioxide of iron of fair quality. It yielded:—
Water 7 per cent.
Sesquioxide 55 per cent.
Earthy matter (chiefly silica) 38 per cent.
The silica (about 20 per cent.) would require lime for its removal. Equal to 38.5 per cent. per metal.

Cromwell.

This sample consists of anhydrous sesquioxide of iron, specular iron ore, mixed with 30 per cent. of quartz and earthy matter. It yielded:—
Sesquioxide 70 per cent.
Silica 22 per cent.
Earthy matter 8 per cent.
This is equal to 49 per cent. of metallic iron. It is, therefore, if in quantity, a valuable ore.

Tokomairiro.

This specimen was forwarded by Capt. Hutton from Tokomairiro. It is an excellent ore. On aualysis it shows of—
Susquioxide of iron 79.5 per cent.
Water 14 0 per cent.
Earthy matter 6.5 per cent.
This is equal to 55.75 per cent. of metallic iron, and in such a state of combination and purity as to be very easily reduced. It will, if found in large quantity be a very valuable ore of iron, and should not be neglected.
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Copper Ores.

Carrick Range.

This sample was forwarded from Carrick by W. Buchan. It is copper pyrites, and coutains 13.5 per cent. of metallic copper. It is at present unavailable, on account of the large quantity of fuel of good quality necessary for its extraction. F[gap — reason: illegible]. Cornwall similar ore of 5 to 10 per cent. of metallic copper is transmitted to Swansea for reduction.

Arrowtown.

This sample was forwarded from Arrowtown through Mr. Willis. It contains 11 per cent. of metallic copper, combined with sulphur and iron as copper pyrites, and containing much earthy impurities. It is too poor to be worked profitably at present.

Moke Creek.

This sample of copper pyrites was examined in September, 1873, for Mr. R. Gillies. It was obtained from Moke Creek, near Queenstown, It contains 24 per cent. of the metal, and is the best specimen of copper pyrites yet examined in this laboratory.

Another sample of copper pyrites from Moke Creek and one from Waipori forwarded by Mr. Ulrich, to be tested for gold, were found to contain that metal, apparently in payable quantity, but there was not in either case a sufficiently large quantity sent to determine the gold quantitatively.

Antimony Ores.

Carrick Range.

These samples from Carrick were forwarded by Mr. Buchan, and were found to contain 50 to 54 per cent. of antimony. The ore of this quality is too far in the interior of the country to be exported profitably. With good fuel, however, it might be freed from the earthy matters with which it is associated, and then conveyed to Dunedin for transmission to Melbourne, where there are, I believe, large works for the reduction of this ore (stibnite) to the metallic state.

Miller’s Flat.

This sample of stibnite was sent from Miller’s Flat by Mr. J. A. Grant in September, 1873. It was found to contain 58 per cent. of metallic antmony, but the sample examined was too small to be taken as an average of the bulk of ore.

Arrow.

This sample, forwarded through A. Willis, Esq., from Arrowtown. It contains 34 per cent. of metal, aud is therefore too poor to work profitably.

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Mercury Ore.

Waipori.

This sample of Cinnabar, forwarded by Mr. R. Gillies, was was obtained from Waipori. It yielded 76 per cent. of metallic mercury.

Another sample was forwarded from Waipori, or Waitahuna, by Mr. Rutherford, and was found to contain 72 per cent. of metallic mercury,

Both these ores, if they exist in quantity, are very valuable. The metal is easily freed, by means of cheap fuel (dried scrub, &c.) and lime from the sulphur with which the mercury is contained in cinnabar. The extensive use of mercury in this Colony and in Victoria for the extraction of gold is an additional reason for not neglecting any ore of that metal that exists in the country.

Waitahuna.

A sample forwarded from Waitahuna, by Mr. R. Smith, contains from 70 to 75 per cent. of mercury, and is therefore very valuable.

Carrick Range.

This sample was forwarded by Mr. W. Buchan, from Carrick. It is the best sample of cinnabar yet analysed in the laboratory. It contains 82 per cent. of the metal. This ore is of great value if present in quantity.

Platinum.
Bluff.

A sample of this ore was forwarded from the Bluff in September, 1873. It consisted of from 35 to 42 per cent. of platinum, black or magnetic oxide of iron not estimated, and an alloy of platinum, osmium, and iridium. The ore, in its present state, is worth in London between 7s. and 9s. per ounce.

Manganese (Black Oxide.)
Taieri Beach.

A sample of this mineral was forwarded from the Taieri beach, by Mr. Hanning, in November, 1873. It was found to contain 90 per cent. of dioxide of manganese. It is, therefore, an excellent specimen of this valuable mineral. It will be very useful when we shall have established in this Colony the manufacture of chloride of lime and other substances that require for their production free chlorine. This will not be done, however, until we can make our own sulphnric acid.

page 150

Oil Shale

Orepuki.

This mineral was forwarded from Orepuki through Mr. Daniel. It was reported on in December, 1873, as follows:—Laminated, very fissile, greyish black, shale flexible in thin layers, densely speckled with mica scales, cuts easily with the knife with unctuous, waxy, section; inflames readily over ignited lucifer match, and maintains after removal of the match a long somewhat smoky flame; the shale shows no trace of woody tissue.

Distilled at low and gradually increasing temperature it yields 42 gallons of crude tarry oil to the ton of shale. This oil possesses the characters of petroleum. It melts at 30°C (86° F.), and at 15°C. (59°F.), has a specific gravity of 0.897. This crude oil, after treatment with sulphuric acid and caustic soda and redistillation, yields from 1 ton of shale 15.2 gallons of purified oil of specific gravity, 0.798 to 0.860, suitable for burning in lamps; also 7 gallons of oil of specific gravity from 86 to 93, suitable for lubricating machinery. At higher temperatures the residue of the above distillation yields a still heavier oil, also suitable for lubricating purposes; finally a liquid tar is obtained, leaving charcoal in the retort. The products of the first distillation are:—
Water 25 per cent.
Earthy residue and charcoal 49.5 per cent.
Crude oil 16.8 per cent.

Dunedin.

This shale was forwarded by Dr. Burns from Burnside, near Blueskin. It is of the same mineral nature as the Orepuki shale, described above. It yields per ton of shale 38 gallons of crude oil. This, when purified by redistillation, after treatment with sulphuric acid and caustic soda in succession, yields per ton of shale about 14 gallons of oil, fit for burning in lamps, and 9 gallons of heavy unctuous oil suitable for lubricating purposes.

If we could produce our own sulphuric acid and soda cheaply, it might be profitable to extract burning and lubricating oils from these shales. As it is, the price of imported acids and alkalis is such as to deter the proprietors of these shales from importing the retorts and other appliances necessary for this purpose.

Felspar.

This specimen was collected by myself, in Port Adventure, Stewart Island. The mineral occurs there in pieces, weighing from 1 lb. to 15 or 20 lbs. These fragments are derived from the disintegration of the granite. Tons of the mineral could be collected with little trouble. It will obviate the necessity of sending for felspar to other countries for pottery and porcelainware purposes. Acting on my suggestion, Mr. White, of Tokomairirc, has sent for page 151a quantity of this felspar, and I understand it is found well adapted for these purposes. The mineral yielded to two of the students of the Laboratory, the following results:—
Mr. Will:
Silica 66.6 per cent.
Alumina 18.6 per cent.
Potash 12.6 per cent.
Soda 2.6 per cent.
Lime Traces.
Magnesia Traces.
100.4
Mr. Solomon.
Silica 58.1 per cent.
Alumina 22.0 per cent.
Potash 11.9 per cent.
Soda 4.3 per cent.
Lime 4.7 per cent.
Magnesia 0.28 per cent.
101.28

The parts analysed were taken from different pieces of mineral.

The large percentage of alkali (15.2 and 16.2 per cont.) makes the stone an excellent flux for glazing in the Pottery Works.

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Geological Map Of the Province of Otago. By F. W. Hutton. Plate V

Geological Map Of the Province of Otago. By F. W. Hutton. Plate V

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Geology Of Otago. Hutton. Plate VI

Geology Of Otago. Hutton. Plate VI

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Geology Of Otago. Hutton. Plate VII

Geology Of Otago. Hutton. Plate VII

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